Poly[μ3-chlorido-μ2-chloridodichlorido(μ-dimethyl sulfoxide-κ2O:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κ2N:N′)ruthenium(III)sodium]
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چکیده
منابع مشابه
Poly[μ3-chlorido-μ2-chloridodichlorido(μ-dimethyl sulfoxide-κ2 O:S)(dimethyl sulfoxide-κO)(μ-pyrimidine-κ2 N:N′)ruthenium(III)sodium]
The title complex, [NaRuCl(4)(C(4)H(4)N(2))(C(2)H(6)OS)(2)](n), is the sodium salt of monoanionic octa-hedral [Ru(III)Cl(4)(pyrimidine)(DMSO)](-) in which the sulfur-bound dimethyl sulfoxide (DMSO) and pyrimidine ligand are oriented trans to one another on the Ru(III) atom. The average of the four Ru-Cl bond lengths is 2.355 (15) Å, and the Ru-S and Ru-N bond lengths are 2.2853 (3) and 2.1165 (...
متن کاملChlorido(dimethyl sulfoxide-κO)triphenyltin(IV)
In the title compound, [Sn(C(6)H(5))(3)Cl(C(2)H(6)OS)], the Sn(IV) atom is coordinated by three phenyl groups, a chloride ion and a dimethyl sulfoxide mol-ecule in a distorted trigonal-bipyramidal geometry. In the crystal, adjacent mol-ecules are linked through inter-molecular C-H⋯Cl hydrogen bonds, weak C-H⋯π inter-actions and π-π inter-actions [centroid-centroid distance = 3.934 (3) Å. An int...
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The title complex, [Ce(C(2)H(6)OS)(8)](2)[Mo(6)O(19)](3)·4C(2)H(6)OS, was obtained as a byproduct of the reaction of [(C(4)H(9))(4)N](2)[Mo(6)O(19)] with Ce(NO(3))(3)·6H(2)O and phthalic acid in dimethyl-sulfoxide solution. The asymmetric unit consists of a complex [Ce(C(2)H(6)OS)(8)](3+) cation, one and a half of the Lindqvist-type [Mo(6)O(19)](2-) polyanions and two dimethyl-sulfoxide solvent...
متن کاملPoly[di-μ2-chlorido-dichlorido(μ3-dimethyl sulfoxide-κ3 O:O:S)(μ2-dimethyl sulfoxide-κ2 O:S)ruthenium(III)sodium]
The structure of the title compound, [NaRuCl(4)(C(2)H(6)OS)(2)](n), comprises centrosymmetric [RuCl(2)(DMSO)Na(DMSO)Cl(2)Ru] units (DMSO is dimethyl sulfoxide, C(2)H(6)OS), with two Ru atoms, each lying on a crystallographic centre of inversion, connected via Na atoms, DMSO and chloride ligands into a two-dimensional (110) array. Both Ru(III) atoms are octa-hedrally coordinated by four chloride...
متن کاملDi-μ-chlorido-bis[chloridobis(dimethyl sulfoxide)dioxidouranium(VI)]
In the crystal structure of the title compound, [U(2)Cl(4)O(4)(C(2)H(6)OS)(4)], the compound has a centrosymmetric dimeric structure bridged by two chloride anions. Each U(VI) atom is seven-coordinate in a penta-gonal-bipyramidal geometry. In the equatorial plane of the uranyl unit there are two O atoms from non-adjacent dimethyl sulfoxides and three chloride ions (of which two chlorides are br...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811017211